Synthesis of Ti3AuC2, Ti3Au2C2 and Ti3IrC2 by noble metal substitution reaction in Ti3SiC2 for high-temperature-stable Ohmic contacts to SiC.

نویسندگان

  • Hossein Fashandi
  • Martin Dahlqvist
  • Jun Lu
  • Justinas Palisaitis
  • Sergei I Simak
  • Igor A Abrikosov
  • Johanna Rosen
  • Lars Hultman
  • Mike Andersson
  • Anita Lloyd Spetz
  • Per Eklund
چکیده

The large class of layered ceramics encompasses both van der Waals (vdW) and non-vdW solids. While intercalation of noble metals in vdW solids is known, formation of compounds by incorporation of noble-metal layers in non-vdW layered solids is largely unexplored. Here, we show formation of Ti3AuC2 and Ti3Au2C2 phases with up to 31% lattice swelling by a substitutional solid-state reaction of Au into Ti3SiC2 single-crystal thin films with simultaneous out-diffusion of Si. Ti3IrC2 is subsequently produced by a substitution reaction of Ir for Au in Ti3Au2C2. These phases form Ohmic electrical contacts to SiC and remain stable after 1,000 h of ageing at 600 °C in air. The present results, by combined analytical electron microscopy and ab initio calculations, open avenues for processing of noble-metal-containing layered ceramics that have not been synthesized from elemental sources, along with tunable properties such as stable electrical contacts for high-temperature power electronics or gas sensors.

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عنوان ژورنال:
  • Nature materials

دوره 16 8  شماره 

صفحات  -

تاریخ انتشار 2017